At All Around Compounding Co., Ltd. (All Around Polymer Co., Ltd.), we specialize in providing high-quality engineering plastics, including nylon composites tailored to meet the diverse needs of our clients. When it comes to selecting nylon materials for various applications, PA6 and PA66 are two of the most commonly used polyamides. Understanding the differences between PA6 vs. PA66, along with their material properties, density, and melting points, can help engineers and manufacturers make informed decisions. This article provides a detailed comparison between PA6 and PA66, focusing on their characteristics, advantages, and typical uses, all based on our extensive industry experience. Whether you're working with PA6 material for its flexibility or exploring the strengths of PA66 in high-stress applications, our guide covers essential insights into these versatile materials.

PA6 vs PA66 - AAP

 

Understanding PA6 and PA66

PA6 (Polyamide 6) and PA66 (Polyamide 66) are both types of nylon, known for their excellent mechanical properties, thermal resistance, and versatility. However, there are distinct differences in their molecular structure and properties that make each suitable for specific applications.

PA6: easier to process due to its lower melting point, making it a cost-effective option for applications that do not require extreme conditions. It also offers better impact resistance and flexibility. However, PA6 has higher water absorption, which can affect its dimensional stability, and it has a lower tensile strength compared to PA66.

PA66: on the other hand, offers superior tensile strength and rigidity, making it ideal for high-temperature applications due to its better thermal resistance. It also absorbs less water than PA6, which helps enhance its dimensional stability. Despite these advantages, PA66 is more challenging to process due to its higher melting point and typically comes at a higher cost compared to PA6.
 

Key Differences Between PA6 and PA66

To provide a clear and detailed comparison, the following chart summarizes the key differences of PA6 and PA66, including properties and applications:

Property PA6 PA66
Molecular Structure Single repeating unit Two repeating units
Density 1.13 1.14
Melting Point (°C) 220 260
Water Absorption Higher Lower
Crystallinity Lower Higher
Tensile Strength (MPa) Lower Higher
Impact Resistance (kJ/m²) Higher Lower
Thermal Stability (°C) Continuous use up to 180°C Continuous use up to 200°C
Processing Temperature (°C) 230 - 250 270 - 290
Molding Temperature (°C) 80 - 100 90 - 120
Molding Shrinkage (%) 0.6 0.8
Heat Deflection Temperature (°C) 170 250
Applications Automotive parts, Office furnitures, Bicycles High-stress automotive parts, Electrical components, Sports equipments
headlight housing
heat shield
chair base
Binoculars
brake lever
Training Wheel/Stabiliser

 




 


 



 

PA6 and PA66: Which to choose?

The choice between Nylon 6 (PA6) and Nylon 66 (PA66) primarily depends on the specific requirements of your project. Both materials offer valuable performance characteristics, and the decision should be based on the application needs, such as strength, rigidity, and heat resistance, referencing the comprehensive comparison chart above.
Below, we provide general guidance on the suitable applications for PA6 and PA66 to give you a foundational understanding of these two materials.

Nylon 6 is known for its high ductility, ease of processing, and cost-effectiveness, making it ideal for general applications.

Nylon 66 offers superior strength, rigidity, and heat resistance.

However, for more demanding requirements, PA6 and PA66 can be modified or reinforced with various fillers to enhance their original properties and expand their range of applications. These modified or reinforced nylons are referred to as nylon compounds, which we will introduce in more detail below.

 

PA6 and PA66 Compounds:

 

How Composites Affect PA6 and PA66?

Compounding PA6 and PA66 can affect their properties in several ways:

 
Composite Type Enhancements
Glass Fiber Reinforced Enhances strength, stiffness, and dimensional stability. Used in automotive components, power tools, and sports equipment.
Mineral-Filled Improves rigidity and thermal stability. Commonly used in electrical housings and structural parts.
Flame-Retardant Provides safety in electrical and electronic applications, used in connectors and switches
Carbon Fiber Reinforced Offers excellent strength-to-weight ratio and electrical conductivity. Used in aerospace, automotive, and high-performance sports equipment.
Impact Modified Increases toughness and resistance to impact forces, reducing fracture risks. Suitable for applications requiring enhanced durability and shock absorption.

nylon compounds

nylon composite

 

Applications of PA6 vs PA66

PA6 and PA66 are widely used in various industries due to their unique properties. Here’s a look at some common applications:

PA6
  • Automotive Industry: PA6 is used in the production of flexible parts such as steering column, seat belt buckle, and side mirror assembly due to its good impact resistance and moderate tensile strength.

  • Office FurniturePA6 is utilized in manufacturing various office furniture components, offering good flexibility and durability.

  • Bicycles: PA6 is employed in the production of bicycle parts, providing necessary flexibility and impact resistance for different components.

headlight housing
headrest
pedal

PA66

  • High-Stress Automotive Parts: PA66 is preferred for high-stress parts such as engine components, manifold, fuel rail and water tank cover owing to its superior tensile strength and higher thermal stability.

  • Electrical ComponentsPA66 is used in connectors, switches, and other high-performance electrical components where rigidity and dimensional stability are crucial.

  • Sports Equipment: PA66 is ideal for applications requiring high mechanical strength and rigidity. It is commonly used in the production of ski bindings, helmets, and protective gear, providing durability and safety in demanding sports environments.

oil tank
Conductor
skate holders

 

Case Study: Tailored Solutions for Our Clients

At All Around Compounding Co., Ltd. (All Around Polymer Co., Ltd.), we pride ourselves on our customer-centric approach and our ability to provide the best material solutions for our clients' needs. Here’s a case study highlighting how we helped a client choose the optimal material for their application: 

Client Background
A leading automotive parts manufacturer approached us with a challenge. They were developing a new line of engine components and were uncertain whether to use PA6 or PA66 for their project. They needed a material that could withstand high temperatures and stress while maintaining dimensional stability.

Our Approach: 

  1. Initial Consultation: We started with a detailed consultation to understand their specific needs, performance requirements, and the operational environment of the components.
  2. Material Analysis: Based on their requirements, we conducted a thorough analysis comparing the properties of PA6 and PA66.
  3. Recommendation: Given the high-stress and high-temperature conditions, we recommended PA66 due to its superior tensile strength, thermal stability, and lower water absorption.
  4. Prototype Development: We assisted in developing prototypes using our high-quality PA66 composites, ensuring they met all performance criteria.
  5. Testing and Feedback: The prototypes were rigorously tested under real-world conditions. The client provided feedback, and we made minor adjustments to optimize performance.
 

Outcome
The client successfully launched their new line of engine components, which performed exceptionally well under high-stress conditions. Our PA66 composites provided the necessary strength and stability, contributing to the product's overall success. The client praised our attentive service, expertise, and the high quality of our materials.

 

Conclusion

Both PA6 and PA66 offer unique advantages depending on the application requirements. PA6 is preferred for applications needing flexibility and impact resistance, while PA66 is ideal for high-stress, high-temperature environments. Understanding these differences, including aspects like PA6's density and melting point, can help manufacturers select the appropriate material to ensure optimal performance and longevity of their products. For example, the difference between PA66 and PA6 may influence the choice in automotive or aerospace applications where weight and material properties are critical.
Moreover, reinforcing PA6 and PA66 with materials like glass fiber, impact modifiers or carbon fibers can significantly enhance their mechanical properties, allowing them to achieve better performance in demanding applications. This reinforcement enables these nylons to handle greater stress and environmental challenges, making them more versatile and reliable for various industrial uses.

Ready to choose the right material for your application? Contact us at info@aaccl.com for expert advice and high-quality PA composite